Application of near critical behavior of equilibrium ratios to phase equilibrium calculations

We examine the asymptotic behavior of the equilibrium ratios (Ki) near the convergence locus in the pressure-temperature plane. When the Equation of State (EoS) is analytical, which is the case of most EoS of engineering purpose, Ki tends towards unity or, equivalently, its logarithm lnKi tends to z...

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Bibliographic Details
Main Authors: Nichita Dan Vladimir, Broseta Daniel, Montel François
Format: Article
Language:English
Published: EDP Sciences 2019-01-01
Series:Oil & Gas Science and Technology
Subjects:
Online Access:https://ogst.ifpenergiesnouvelles.fr/articles/ogst/full_html/2019/01/ogst190185/ogst190185.html