General Intermediates for the Synthesis of 6-C-Alkylated DMDP-Related Natural Products

Protected L-homoDMDP en-8 and its C-6 epimer en-7 were prepared through two different pathways starting from the vinylpyrrolidine en-9. Based on the NMR and X-ray analysis, the stereochemistry of homoDMDP at C-6 was confirmed to be consistent with reported data. Compounds en-7 and en-8 are general i...

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Bibliographic Details
Main Authors: Chu-Yi Yu, Yue-Mei Jia, Yi-Xian Li, Mu-Hua Huang
Format: Article
Language:English
Published: MDPI AG 2013-06-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/18/6/6723