RuO4-mediated oxidation of secondary amines 2. imines as main reaction intermediates

RuO4-mediated oxidation of secondary amines 2. imines as main reaction intermediates

Oxidation by RuO4 (generated in situ from RuO2 and NaIO4) of secondary amines such as Bn–NH–CH2R (1; R=H, Me) gave complex reaction mixtures, but mainly amides. In the presence of cyanide, the leading products were α-aminonitriles. Comparison of the oxidation products of 1 with those from the corres...

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Bibliographic Details
Main Authors: Florea Cristina A., Hîrtopeanu Anca, Stavarache Cristina, Petride Horia
Format: Article
Language:English
Published: Serbian Chemical Society 2017-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
oxidation
secondary amines
ruthenium tetraoxide
imines
α-aminonitriles
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2017/0352-51391700055F.pdf

Internet

http://www.doiserbia.nb.rs/img/doi/0352-5139/2017/0352-51391700055F.pdf

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