Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling

Migratory cross-coupling reactions are powerful tools to form bonds at predictable positions. Here the authors report a nickel-catalyzed migratory Suzuki–Miyaura cross-coupling of unactivated alkyl electrophiles with aryl and vinyl boron reagents and provide experimental and computational mechanisti...

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Bibliographic Details
Main Authors: Yuqiang Li, Yixin Luo, Long Peng, Yangyang Li, Binzhi Zhao, Wang Wang, Hailiang Pang, Yi Deng, Ruopeng Bai, Yu Lan, Guoyin Yin
Format: Article
Language:English
Published: Nature Publishing Group 2020-01-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-019-14016-1