An Asymmetrically Substituted Aliphatic Bis-Dithiolene Mono-Oxido Molybdenum(IV) Complex With Ester and Alcohol Functions as Structural and Functional Active Site Model of Molybdoenzymes

An Asymmetrically Substituted Aliphatic Bis-Dithiolene Mono-Oxido Molybdenum(IV) Complex With Ester and Alcohol Functions as Structural and Functional Active Site Model of Molybdoenzymes

A MoIV mono-oxido bis-dithiolene complex, [MoO(mohdt)2]2− (mohdt = 1-methoxy-1-oxo-4-hydroxy-but-2-ene-2,3-bis-thiolate) was synthesized as a structural and functional model for molybdenum oxidoreductase enzymes of the DMSO reductase family. It was comprehensively characterized by inter alia various...

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Bibliographic Details
Main Authors: Mohsen Ahmadi, Christian Fischer, Ashta C. Ghosh, Carola Schulzke
Format: Article
Language:English
Published: Frontiers Media S.A. 2019-07-01
Series:Frontiers in Chemistry
Subjects:
artificial molybdenum active site
aliphatic dithiolene
oxygen atom transfer
Moco model
MoIV oxo complex
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2019.00486/full

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https://www.frontiersin.org/article/10.3389/fchem.2019.00486/full

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