Crystal structures of (acetonitrile-κN)tris(pyridine-4-thioamide-κN)bis(thiocyanate-κN)cobalt(II) acetonitrile disolvate and tetrakis(pyridine-4-thioamide-κN)bis(thiocyanate-κN)nickel(II) methanol pentasolvate

Crystal structures of (acetonitrile-κN)tris(pyridine-4-thioamide-κN)bis(thiocyanate-κN)cobalt(II) acetonitrile disolvate and tetrakis(pyridine-4-thioamide-κN)bis(thiocyanate-κN)nickel(II) methanol pentasolvate

Reaction of Co(NCS)2 or Ni(NCS)2 with pyridine-4-thioamide in different solvents led to the formation of two compounds with composition [Co(NCS)2(C2H3N)(C6H6N2S)3]·2CH3CN (1) and [Ni(NCS)2(C6H6N2S)4]·5CH3OH (2), respectively. The asymmetric unit of compound 1 consists of one cobalt(II) cation, two t...

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Bibliographic Details
Main Authors: Tristan Neumann, Inke Jess, Christian Näther
Format: Article
Language:English
Published: International Union of Crystallography 2018-07-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
discrete complexes
thiocyanate
hydrogen bonding
cobalt
nickel
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018007612

Internet

http://scripts.iucr.org/cgi-bin/paper?S2056989018007612

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