Synthesis and structural characterization of four dichloridobis(cyclopropylalkynylamidine)metal complexes

Synthesis and structural characterization of four dichloridobis(cyclopropylalkynylamidine)metal complexes

Deliberate hydrolysis of lithium cyclopropylalkynylamidinates, Li[c-C3H5—C[triple-bond]C(NR′)2] [R′ = iPr, Cy = cyclohexyl)], afforded the hitherto unknown neutral cyclopropylalkynylamidine derivatives c-C3H5—C[triple-bond]C—C(NR′)(NHR′) [R′ = iPr (1), Cy (2)]. Subsequent reactions of 1 or 2 with me...

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Bibliographic Details
Main Authors: Sida Wang, Phil Liebing, Felix Engelhardt, Liane Hilfert, Sabine Busse, Frank T. Edelmann
Format: Article
Language:English
Published: International Union of Crystallography 2018-11-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
amidinate ligand
amidine
manganese
iron
cobalt
crystal structure
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018014895

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http://scripts.iucr.org/cgi-bin/paper?S2056989018014895

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