Reactions of 2-carbonyl- and 2-hydroxy(or methoxy)alkyl-substituted benzimidazoles with arenes in the superacid CF3SO3H. NMR and DFT studies of dicationic electrophilic species

Reactions of 2-carbonyl- and 2-hydroxy(or methoxy)alkyl-substituted benzimidazoles with arenes in the superacid CF3SO3H. NMR and DFT studies of dicationic electrophilic species

Reactions of 2-carbonyl- and 2-hydroxy(or methoxy)alkylbenzimidazoles with arenes in the Brønsted superacid TfOH resulted in the formation of the corresponding Friedel–Crafts reaction products, 2-diarylmethyl and 2-arylmethyl-substituted benzimidazoles, in yields up to 90%. The reaction intermediate...

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Bibliographic Details
Main Authors: Dmitry S. Ryabukhin, Alexey N. Turdakov, Natalia S. Soldatova, Mikhail O. Kompanets, Alexander Yu. Ivanov, Irina A. Boyarskaya, Aleksander V. Vasilyev
Format: Article
Language:English
Published: Beilstein-Institut 2019-08-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
benzimidazoles
cations
Friedel–Crafts reaction
triflic acid
Online Access:https://doi.org/10.3762/bjoc.15.191

Internet

https://doi.org/10.3762/bjoc.15.191

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