A superior P-H phosphonite: Asymmetric allylic substitutions with fenchol-based palladium catalysts

The fenchol-based P-H phosphonite BIFOP-H exeeds with 65% ee other monodentate ligands in the Pd-catalyzed substitution of 1-phenyl-2-propenyl acetate with dimethylmalonate.

Bibliographic Details
Main Authors: Bernd Goldfuss, Thomas Löschmann, Tina Kop-Weiershausen, Jörg Neudörfl, Frank Rominger
Format: Article
Language:English
Published: Beilstein-Institut 2006-03-01
Series:Beilstein Journal of Organic Chemistry
Online Access:https://doi.org/10.1186/1860-5397-2-7