C–H Bond Activation of Silyl-Substituted Pyridines with Bis(Phenolate)Yttrium Catalysts as a Facile Tool towards Hydroxyl-Terminated Michael-Type Polymers

C–H Bond Activation of Silyl-Substituted Pyridines with Bis(Phenolate)Yttrium Catalysts as a Facile Tool towards Hydroxyl-Terminated Michael-Type Polymers

Herein, silicon-protected, <i>ortho</i>-methylated hydroxy-pyridines were reported as initiators in 2-aminoalkoxy-bis(phenolate)yttrium complexes for rare earth metal-mediated group-transfer polymerization (REM-GTP) of Michael-type monomers. To introduce these initiators, C−H bond activa...

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Bibliographic Details
Main Authors: Thomas M. Pehl, Moritz Kränzlein, Friederike Adams, Andreas Schaffer, Bernhard Rieger
Format: Article
Language:English
Published: MDPI AG 2020-04-01
Series:Catalysts
Subjects:
rare earth metal-mediated group-transfer polymerization
homogeneous catalysis
C–H bond activation
end-group functionalization
poly(diethyl vinyl phosphonate)
poly(2-vinylpyridine)
Online Access:https://www.mdpi.com/2073-4344/10/4/448

Internet

https://www.mdpi.com/2073-4344/10/4/448

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