Identification of the dominant photochemical pathways and mechanistic insights to the ultrafast ligand exchange of Fe(CO)5 to Fe(CO)4EtOH

Identification of the dominant photochemical pathways and mechanistic insights to the ultrafast ligand exchange of Fe(CO)5 to Fe(CO)4EtOH

We utilized femtosecond time-resolved resonant inelastic X-ray scattering and ab initio theory to study the transient electronic structure and the photoinduced molecular dynamics of a model metal carbonyl photocatalyst Fe(CO)5 in ethanol solution. We propose mechanistic explanation for the parallel...

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Bibliographic Details
Main Authors: K. Kunnus, I. Josefsson, I. Rajkovic, S. Schreck, W. Quevedo, M. Beye, C. Weniger, S. Grübel, M. Scholz, D. Nordlund, W. Zhang, R. W. Hartsock, K. J. Gaffney, W. F. Schlotter, J. J. Turner, B. Kennedy, F. Hennies, F. M. F. de Groot, S. Techert, M. Odelius, Ph. Wernet, A. Föhlisch
Format: Article
Language:English
Published: AIP Publishing LLC and ACA 2016-07-01
Series:Structural Dynamics
Online Access:http://dx.doi.org/10.1063/1.4941602

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http://dx.doi.org/10.1063/1.4941602

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