Investigation of Microstructure and Nanoindentation Hardness of C⁺ & He⁺ Irradiated Nanocrystal SiC Coatings during Annealing and Corrosion

• Main Authors: Guiliang Liu, Yipeng Li, Zongbei He, Yang Chen, Shuo Cong, Zhaoke Chen, Xiuyin Huang, Ruiqian Zhang, Guang Ran
• Format: Article
• Language: English
• Published: MDPI AG 2020-12-01
• Series: Materials
• Subjects: SiC coating; ion irradiation; microstructure; bubbles; nanoindentation hardness
• Online Access: https://www.mdpi.com/1996-1944/13/23/5567

The microstructure and nanoindentation hardness of unirradiated, irradiated, annealed and corroded SiC coatings were characterized. Irradiation of 400 keV C⁺ and 200 keV He⁺ with approximately 10 dpa did not cause obvious amorphous transformation to nanocrystal SiC coatings and induced helium bubbles with 2–3 nm dimension distributed uniformly in the SiC matrix. High temperature annealing resulted in the transformation of SiC nanocrystals into columnar crystals in the irradiated region. Line-shaped bubble bands formed at the columnar crystal boundaries and their stacking fault planes and made the formation of microcracks of hundreds of nanometers in length. Meanwhile, some isolated helium bubbles distributed in SiC grains still maintained a size of 2–3 nm, despite annealing at 1200 °C for 5 h. The SiC coating showed excellent corrosion resistance under high-temperature, high-pressure water. The weight of the sample decreased with the increase of corrosion time. The nanoindentation hardness and the elastic modulus increased significantly with C⁺ and He⁺ irradiation, while their values decreased with high-temperature annealing. An increase in the annealing temperature led to an increased reduction in the values. Corrosion caused the decrease of nanoindentation hardness and the elastic modulus in the whole test depth range, whether the samples were irradiated or unirradiated.