Di-μ-cyanido-1:2κ2C:N,2:3κ2N:C-hexacyanido-1κ3C,3κ3C-tetrakis(1,10-phenanthroline)-1κ2N,N′;2κ4N,N′;3κ2N,N′-1,3-dicobalt(III)-2-iron(II) tetrahydrate

Di-μ-cyanido-1:2κ2C:N,2:3κ2N:C-hexacyanido-1κ3C,3κ3C-tetrakis(1,10-phenanthroline)-1κ2N,N′;2κ4N,N′;3κ2N,N′-1,3-dicobalt(III)-2-iron(II) tetrahydrate

The hydrothermal reaction of CoCl2·6H2O, 1,10-phenanthroline (phen) and K3[Fe(CN)6] in deionized water yielded the title cyanide-bridged trinuclear cluster, [Co2Fe(CN)8(C12H8N2)4]·4H2O or [{CoIII(phen)(CN)4}2{FeII(phen)2}]·4H2O, which contains two CoIII centers...

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Bibliographic Details
Main Authors: Ying Zhang, Ai-Hua Yuan, Hu Zhou, Ji-Xi Guo, Lang Liu
Format: Article
Language:English
Published: International Union of Crystallography 2009-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809030165

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http://scripts.iucr.org/cgi-bin/paper?S1600536809030165

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