Anionic redox reaction in layered NaCr2/3Ti1/3S2 through electron holes formation and dimerization of S–S

Anionic redox reaction in layered NaCr2/3Ti1/3S2 through electron holes formation and dimerization of S–S

Anionic redox reactions are gaining interest as a means to optimize capacities of alkaline ion batteries. Here, the authors investigate various charge compensation mechanisms and report S–S dimerization and the formation of electron holes on sulfur in a model sulfide cathode.

Bibliographic Details
Main Authors: Tian Wang, Guo-Xi Ren, Zulipiya Shadike, Ji-Li Yue, Ming-Hui Cao, Jie-Nan Zhang, Ming-Wei Chen, Xiao-Qing Yang, Seong-Min Bak, Paul Northrup, Pan Liu, Xiao-Song Liu, Zheng-Wen Fu
Format: Article
Language:English
Published: Nature Publishing Group 2019-10-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-019-12310-6

Internet

https://doi.org/10.1038/s41467-019-12310-6

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