On the Tautomerism of N-Substituted Pyrazolones: 1,2-Dihydro-3H-pyrazol-3-ones versus 1H-Pyrazol-3-ols

On the Tautomerism of N-Substituted Pyrazolones: 1,2-Dihydro-3H-pyrazol-3-ones versus 1H-Pyrazol-3-ols

The tautomerism of 1-phenyl-1,2-dihydro-3H-pyrazol-3-One was investigated. An X-ray crystal structure analysis exhibits dimers of 1-phenyl-1H-pyrazol-3-ol units. Comparison of NMR (nuclear magnetic resonance) spectra in liquid state (1H, 13C, 15N) with those of “fixed” derivatives, as well as with t...

Full description

Bibliographic Details
Main Authors: Eglė Arbačiauskienė, Sonata Krikštolaitytė, Aiva Mitrulevičienė, Aurimas Bieliauskas, Vytas Martynaitis, Matthias Bechmann, Alexander Roller, Algirdas Šačkus, Wolfgang Holzer
Format: Article
Language:English
Published: MDPI AG 2018-01-01
Series:Molecules
Subjects:
prototropic tautomerism
1H-pyrazol-3-ol
1,2-dihydro-3H-pyrazol-3-ones
NMR (1H
13C
15N)
solid state NMR
X-ray structure analysis
Online Access:http://www.mdpi.com/1420-3049/23/1/129

Internet

http://www.mdpi.com/1420-3049/23/1/129

Similar Items