A new monoclinic polymorph of 1,1′-bis(diphenylthiophosphoryl)ferrocene

The title compound, [Fe(C17H14PS)2], is a second monoclinic polymorph (P21/c, with Z′ = 1) of the previously reported monoclinic (C2/c, with Z′ = 1/2) form [Fang et al. (1995). Polyhedron, 14, 2403–2409]. In the new form, the S atoms lie to the same side of the molecule with the pseudo S—P...P—S tor...

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Bibliographic Details
Main Authors: Yee Seng Tan, Chien Ing Yeo, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2015-08-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015012682