Post-Synthetic Shaping of Porosity and Crystal Structure of Ln-Bipy-MOFs by Thermal Treatment
The reaction of anhydrous lanthanide chlorides together with 4,4′-bipyridine yields the MOFs 2∞[Ln2Cl6(bipy)3]·2bipy, with Ln = Pr − Yb, bipy = 4,4′-bipyridine, and 3∞[La2Cl6(bipy)5]·4bipy. Post-synthetic thermal treatment in combination with different vacuum conditions was successfully used to shap...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2015-07-01
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| Series: | Molecules |
| Subjects: | |
| Online Access: | http://www.mdpi.com/1420-3049/20/7/12125 |