Chirogenesis and Pfeiffer Effect in Optically Inactive EuIII and TbIII Tris(β-diketonate) Upon Intermolecular Chirality Transfer From Poly- and Monosaccharide Alkyl Esters and α-Pinene: Emerging Circularly Polarized Luminescence (CPL) and Circular Dichroism (CD)

Chirogenesis and Pfeiffer Effect in Optically Inactive EuIII and TbIII Tris(β-diketonate) Upon Intermolecular Chirality Transfer From Poly- and Monosaccharide Alkyl Esters and α-Pinene: Emerging Circularly Polarized Luminescence (CPL) and Circular Dichroism (CD)

We report emerging circularly polarized luminescence (CPL) at 4f-4f transitions when lanthanide (EuIII and TbIII) tris(β-diketonate) embedded to cellulose triacetate (CTA), cellulose acetate butyrate (CABu), D-/L-glucose pentamethyl esters (D-/L-Glu), and D-/L-arabinose tetramethyl esters (D-/L-Ara)...

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Bibliographic Details
Main Authors: Michiya Fujiki, Laibing Wang, Nanami Ogata, Fumio Asanoma, Asuka Okubo, Shun Okazaki, Hiroki Kamite, Abd Jalil Jalilah
Format: Article
Language:English
Published: Frontiers Media S.A. 2020-08-01
Series:Frontiers in Chemistry
Subjects:
non-covalent interaction
circularly polarized luminescence
circular dichroism
europium
terbium
cellulose
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2020.00685/full

Internet

https://www.frontiersin.org/article/10.3389/fchem.2020.00685/full

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