Pentacarbonyl-1κ2C,2κ3C-(μ-pyrazine-2,3-dithiolato-1:2κ4S,S′:S,S′)(trimethylphosphane-1κP)diiron(I)(Fe—Fe)

In the title compound, [Fe2(C4H2N2S2)(C3H9P)(CO)5], the Fe2S2 core adopts a butterfly conformation. The PMe3 ligand is coordinated in the basal position, roughly cis to the Fe—Fe bond. The Fe—Fe distance of 2.4970 (6) Å is relative...

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Bibliographic Details
Main Authors: Shang Gao, Chun-Ai An, Qian Duan, Da-Yong Jiang
Format: Article
Language:English
Published: International Union of Crystallography 2011-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811046770