On the cause of low thermal stability of ethyl halodiazoacetates

On the cause of low thermal stability of ethyl halodiazoacetates

Rates for the thermal decomposition of ethyl halodiazoacetates (halo = Cl, Br, I) have been obtained, and reported herein are their half-lives. The experimental results are supported by DFT calculations, and we provide a possible explanation for the reduced thermal stability of ethyl halodiazoacetat...

Full description

Bibliographic Details
Main Authors: Magnus Mortén, Martin Hennum, Tore Bonge-Hansen
Format: Article
Language:English
Published: Beilstein-Institut 2016-07-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
carbenes
catalysis
cyclopropanation
halo diazoacetates
half-lives
thermal stability
Online Access:https://doi.org/10.3762/bjoc.12.155

Internet

https://doi.org/10.3762/bjoc.12.155

Similar Items