Efficient Synthesis of an Aluminum Amidoborane Ammoniate

Efficient Synthesis of an Aluminum Amidoborane Ammoniate

A novel species of metal amidoborane ammoniate, [Al(NH2BH3)63−][Al(NH3)63+] has been successfully synthesized in up to 95% via the one-step reaction of AlH3·OEt2 with liquid NH3BH3·nNH3 (n = 1~6) at 0 °C. This solution based reaction method provides an alternative pathway to the traditional mechano-...

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Bibliographic Details
Main Authors: Junzhi Yang, Paul R. Beaumont, Terry D. Humphries, Craig M. Jensen, Xingguo Li
Format: Article
Language:English
Published: MDPI AG 2015-08-01
Series:Energies
Subjects:
aluminum
amidoborane
boranes
dehydrogenation
hydrogen storage
synthetic methods
Nuclear Magnetic Resonance Spectroscopy (NMR)
Online Access:http://www.mdpi.com/1996-1073/8/9/9107

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http://www.mdpi.com/1996-1073/8/9/9107

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