Tuning of Hula-Hoop Coordination Geometry in a Dy Dimer
The reaction of DyCl3 with hydrazone Schiff base ligands and sodium acetate in the presence of triethylamine (Et3N) as base affords two dysprosium dimers: [Dy2(HL1)2(OAc)2(EtOH)(MeOH)] (1) and [Dy2(L2)2(OAc)2(H2O)2]·2MeOH (2). The DyIII ions in complexes 1 and 2 are linked by alkoxo bridges, and dis...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
Published: |
MDPI AG
2016-01-01
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Series: | Inorganics |
Subjects: | |
Online Access: | http://www.mdpi.com/2304-6740/4/1/2 |