Tuning of Hula-Hoop Coordination Geometry in a Dy Dimer

The reaction of DyCl3 with hydrazone Schiff base ligands and sodium acetate in the presence of triethylamine (Et3N) as base affords two dysprosium dimers: [Dy2(HL1)2(OAc)2(EtOH)(MeOH)] (1) and [Dy2(L2)2(OAc)2(H2O)2]·2MeOH (2). The DyIII ions in complexes 1 and 2 are linked by alkoxo bridges, and dis...

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Bibliographic Details
Main Authors: Yan Peng, Valeriu Mereacre, Christopher E. Anson, Annie K. Powell
Format: Article
Language:English
Published: MDPI AG 2016-01-01
Series:Inorganics
Subjects:
Online Access:http://www.mdpi.com/2304-6740/4/1/2