Diastereoselective [2+2] Photocycloaddition of Chiral Cyclic Enones with Olefins in Aqueous Media Using Surfactants

Diastereoselective [2+2] Photocycloaddition of Chiral Cyclic Enones with Olefins in Aqueous Media Using Surfactants

We conducted diastereodifferentiating [2+2] photocycloadditions of cyclo-hexenones modified with a chiral 8-(p-methoxy phenyl)menthyl auxiliary with olefins in water. Although the photoreaction didn’t proceed at all in pure water owing to very low solubility, the use of surfactants [sodium dodecyl s...

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Bibliographic Details
Main Authors: Yasuhiro Nishiyama, Mikiko Shibata, Takuya Ishii, Tsumoru Morimoto, Hiroki Tanimoto, Ken Tsutsumi, Kiyomi Kakiuchi
Format: Article
Language:English
Published: MDPI AG 2013-01-01
Series:Molecules
Subjects:
diastereoselectivity
[2+2] photocycloaddition
aqueous media
surfactant
Online Access:http://www.mdpi.com/1420-3049/18/2/1626

Internet

http://www.mdpi.com/1420-3049/18/2/1626

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