Steric effects on the rate of hydrolysis by palladium(II) complexes of the C-terminal amide bond in a series of methionine-containing dipeptides AcMet-Aa

Steric effects on the rate of hydrolysis by palladium(II) complexes of the C-terminal amide bond in a series of methionine-containing dipeptides AcMet-Aa

A series of N-acetylated, methionine-containing dipeptides designated AcMet-Aa containing various C-terminal amino acids designated Aa are hydrolyzed in aqueous solution at 50 ºC and 0.95 < pD < 1.10 in the presence of three cis-[Pd(L)(H2O)2]2+ complexes, in which L are bidentate ligands en Me...

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Bibliographic Details
Main Authors: Johnson Wade T., Kostić Nenad M.
Format: Article
Language:English
Published: Serbian Chemical Society 2004-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
selective cleavage
kinetics
peptides
methionine
palladium(ii).
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2004/0352-51390411887J.pdf

Internet

http://www.doiserbia.nb.rs/img/doi/0352-5139/2004/0352-51390411887J.pdf

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