Substituent Effects of Phenyl Group on Silylene Bridge in Stereospecific Polymerization of Propylene with C1-Symmetric Ansa-Silylene(fluorenyl)(amido) Dimethyl Titanium Complexes

Substituent Effects of Phenyl Group on Silylene Bridge in Stereospecific Polymerization of Propylene with C1-Symmetric Ansa-Silylene(fluorenyl)(amido) Dimethyl Titanium Complexes

A C1-symmetric (methylphenyl)silylene-bridged (fluorenyl)(naphthylamido) titanium complex (1) and (diphenyl)silylene-bridged (fluorenyl)(naphthylamido) titanium complex (2) were synthesized and characterized by 1H NMR, element analysis, and X-ray crystal analysis. The coordination mode of the fluore...

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Bibliographic Details
Main Authors: Huajin Wang, Yanqing Li, Zhengguo Cai
Format: Article
Language:English
Published: MDPI AG 2018-09-01
Series:Polymers
Subjects:
C1-symmetric
titanium complex
propylene polymerization
stereospecific
Online Access:http://www.mdpi.com/2073-4360/10/10/1075

Internet

http://www.mdpi.com/2073-4360/10/10/1075

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