Chemically Induced Dynamic Nuclear Polarization during the Thermolysis of Alkoxyamines: A New Approach to Detect the Occurrence of H-Transfer Reactions

Thermal decomposition of alkoxyamines in the presence of scavengers was found to proceed with the formation of chemically induced nuclear polarization detected by 1H NMR. The distinctive Chemically Induced Dynamic Nuclear Polarization (CIDNP) features were studied using the example of three alkoxyam...

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Bibliographic Details
Main Authors: Elena Bagryanskaya, Yohann Guillaneuf, Didier Gigmes, Denis Bertin, Maria Edeleva, Sylvain R. A. Marque
Format: Article
Language:English
Published: MDPI AG 2010-09-01
Series:Polymers
Subjects:
Online Access:http://www.mdpi.com/2073-4360/2/4/364/