Grubbs–Hoveyda type catalysts bearing a dicationic N-heterocyclic carbene for biphasic olefin metathesis reactions in ionic liquids

Grubbs–Hoveyda type catalysts bearing a dicationic N-heterocyclic carbene for biphasic olefin metathesis reactions in ionic liquids

The novel dicationic metathesis catalyst [(RuCl2(H2ITapMe2)(=CH–2-(2-PrO)-C6H4))2+ (OTf−)2] (Ru-2, H2ITapMe2 = 1,3-bis(2’,6’-dimethyl-4’-trimethylammoniumphenyl)-4,5-dihydroimidazol-2-ylidene, OTf− = CF3SO3−) based on a dicationic N-heterocyclic carbene (NHC) ligand was prepared. The reactivity was...

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Bibliographic Details
Main Authors: Maximilian Koy, Hagen J. Altmann, Benjamin Autenrieth, Wolfgang Frey, Michael R. Buchmeiser
Format: Article
Language:English
Published: Beilstein-Institut 2015-09-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
biphasic catalysis
ionic initiators
recycling
ROMP
ruthenium
Online Access:https://doi.org/10.3762/bjoc.11.178

Internet

https://doi.org/10.3762/bjoc.11.178

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