Further Studies on the Pyrolytic Domino Cyclization of Stabilized Phosphonium Ylides Bearing an Ortho-Aminophenyl Group

Further Studies on the Pyrolytic Domino Cyclization of Stabilized Phosphonium Ylides Bearing an Ortho-Aminophenyl Group

Four new, stabilized phosphonium ylides containing a 2-(benzyl(methyl)amino)phenyl group have been prepared and characterized and are found, upon pyrolysis under gas-phase flow conditions, to lose Ph3PO and benzyl radicals to afford new heterocyclic products resulting from domino cyclization of both...

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Bibliographic Details
Main Authors: R. Alan Aitken, Lorna Murray, Alexandra M. Z. Slawin
Format: Article
Language:English
Published: MDPI AG 2018-08-01
Series:Molecules
Subjects:
phosphonium ylide
pyrolysis
quinoline
phenanthridine
benzocarbazole
X-ray structure
Online Access:http://www.mdpi.com/1420-3049/23/9/2153

Internet

http://www.mdpi.com/1420-3049/23/9/2153

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