Dramatic Effect of A Ring Size of Alicyclic α-Dioximate Ligand Synthons on Kinetics of the Template Synthesis and of the Acidic Decomposition of the Methylboron-Capped Iron(II) Clathrochelates

Dramatic Effect of A Ring Size of Alicyclic α-Dioximate Ligand Synthons on Kinetics of the Template Synthesis and of the Acidic Decomposition of the Methylboron-Capped Iron(II) Clathrochelates

Kinetics and thermodynamics of the template synthesis and of the acidic decomposition of the methylboron-capped iron(II) tris-1,2-dioximates—the clathrochelate derivatives of six (nioxime)- and eight (octoxime)-membered alicyclic ligand synthons—were compared. In the case of a macrobicyclic iron(II)...

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Bibliographic Details
Main Authors: Alexander L. Pomadchik, Alexander S. Belov, Ekaterina G. Lebed, Irina G. Belaya, Anna V. Vologzhanina, Yan Z. Voloshin
Format: Article
Language:English
Published: MDPI AG 2021-06-01
Series:Molecules
Subjects:
macrocyclic compounds
cage complexes
clathrochelates
iron complexes
template synthesis
acidic decomposition
Online Access:https://www.mdpi.com/1420-3049/26/13/4019

Internet

https://www.mdpi.com/1420-3049/26/13/4019

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