Photoredox-catalyzed silyldifluoromethylation of silyl enol ethers

A method for the light-mediated fluoroalkylation of silyl enol ethers with (bromodifluoromethyl)trimethylsilane followed by a reduction of the primary products with sodium borohydride is described. An 18 W, 375 nm LED was used as the light source. The reaction is performed in the presence of a gold...

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Bibliographic Details
Main Authors: Vyacheslav I. Supranovich, Vitalij V. Levin, Alexander D. Dilman
Format: Article
Language:English
Published: Beilstein-Institut 2020-06-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.16.126