Molecular structures of pyridinethiolato complexes of Sn(II), Sn(IV), Ge(IV), and Si(IV)

Complexes of Sn(II), Sn(IV), Ge(IV), and Si(IV) with the ambidentate pyridine-2-thiolato ligand (PyS-) were synthesized and characterized by multinuclear NMR spectroscopy and single-crystal X-ray diffractometry. Comparison of the structures of E(PyS)2Cl2 (E=Sn, Ge, Si) and E(PyS)4 (E=Sn, Si) allows...

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Bibliographic Details
Main Authors: Wächtler Erik, Gericke Robert, Kutter Silvio, Brendler Erica, Wagler Jörg
Format: Article
Language:English
Published: De Gruyter 2013-12-01
Series:Main Group Metal Chemistry
Subjects:
tin
Online Access:https://doi.org/10.1515/mgmc-2013-0041