Water in crystalline fibers of dihydrate β-chitin results in unexpected absence of intramolecular hydrogen bonding.

The complete crystal structure (including hydrogen) of dihydrate β-chitin, a homopolymer of N-acetylglucosamine hydrate, was determined using high-resolution X-ray and neutron fiber diffraction data collected from bathophilous tubeworm Lamellibrachia satsuma. Two water molecules per N-acetylglucosam...

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Bibliographic Details
Main Authors: Daisuke Sawada, Yoshiharu Nishiyama, Paul Langan, V Trevor Forsyth, Satoshi Kimura, Masahisa Wada
Format: Article
Language:English
Published: Public Library of Science (PLoS) 2012-01-01
Series:PLoS ONE
Online Access:http://europepmc.org/articles/PMC3378566?pdf=render