Isolation and X-ray characterization of palladium–N complexes in the guanylation of aromatic amines. Mechanistic implications

Isolation and X-ray characterization of palladium–N complexes in the guanylation of aromatic amines. Mechanistic implications

In the context of palladium-catalyzed guanylation of anilines herein, we have been able to characterize and isolate bis(anilino) and bis(guanidino)Pd(II) complexes using reaction conditions under which stoichiometric amounts of palladium salts are used. Characterization of these palladium complexes...

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Bibliographic Details
Main Authors: Abdessamad Grirrane, Hermenegildo Garcia, Eleuterio Álvarez
Format: Article
Language:English
Published: Beilstein-Institut 2013-07-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
coordination chemistry
guanylation reaction
homogeneous catalysis
palladium complexes
reactive intermediates
Online Access:https://doi.org/10.3762/bjoc.9.165

Internet

https://doi.org/10.3762/bjoc.9.165

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