Selective formation of a zwitterion adduct and bicarbonate salt in the efficient CO2 fixation by N-benzyl cyclic guanidine under dry and wet conditions

Selective formation of a zwitterion adduct and bicarbonate salt in the efficient CO2 fixation by N-benzyl cyclic guanidine under dry and wet conditions

The efficient CO2 fixation by N-benzyl cyclic guanidine 1 was achieved by bubbling dry CO2 through CH3CN at 25 °C for 2 h. In addition, the zwitterion adduct 2 and bicarbonate salt 3 were selectively prepared from 1 under dry (in anhydrous CH3CN) and wet (in CH3CN containing an equimolar amount of w...

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Bibliographic Details
Main Authors: Yoshiaki Yoshida, Naoto Aoyagi, Takeshi Endo
Format: Article
Language:English
Published: Beilstein-Institut 2018-08-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
bicarbonate salt
carbon dioxide adsorption
cyclic guanidine
repeatable capture and release
zwitterion adduct
Online Access:https://doi.org/10.3762/bjoc.14.194

Internet

https://doi.org/10.3762/bjoc.14.194

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