Efficient catalytic alkyne metathesis with a fluoroalkoxy-supported ditungsten(III) complex

Efficient catalytic alkyne metathesis with a fluoroalkoxy-supported ditungsten(III) complex

The molybdenum and tungsten complexes M2(OR)6 (Mo2F6, M = Mo, R = C(CF3)2Me; W2F3, M = W, R = OC(CF3)Me2) were synthesized as bimetallic congeners of the highly active alkyne metathesis catalysts [MesC≡M{OC(CF3)nMe3−n}] (MoF6, M = Mo, n = 2; WF3, M = W, n = 1; Mes = 2,4,6-trimethylphenyl). The corre...

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Bibliographic Details
Main Authors: Henrike Ehrhorn, Janin Schlösser, Dirk Bockfeld, Matthias Tamm
Format: Article
Language:English
Published: Beilstein-Institut 2018-09-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
alkylidyne complexes
alkyne metathesis
catalysis
terminal alkynes
tungsten
Online Access:https://doi.org/10.3762/bjoc.14.220

Internet

https://doi.org/10.3762/bjoc.14.220

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