Hexakis(2-amino-4-methylpyridine-κN1)dioxidohexa-μ4-sulfido-hexacopper(I)divanadium(V)

The title compound, [Cu6V2O2S6(C6H8N2)6], is constructed from six CuS3N and two VOS3 distorted tetrahedra, forming an octanuclear V/S/Cu cluster with Ci symmetry. The geometry around the V atoms is slightly distorted tetrahedral, while there are large distortions from ideal tetrahedral geometry for...

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Bibliographic Details
Main Authors: Zhengjing Jiang, Jianying Zhao, Guodong Tang, Zhang Yu
Format: Article
Language:English
Published: International Union of Crystallography 2008-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808027165