Identifying the missing link in catalyst transfer polymerization
The mechanism for nickel-catalyzed catalyst transfer polycondensation of thiophenes to polythiophenes. Here the authors show experimental and computational evidence of structurally characterized square planar η 2-Ni(0)–thiophene species and their relevance to the mechanism of catalyst transfer polyc...
Main Authors: | Weiying He, Brian O. Patrick, Pierre Kennepohl |
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Format: | Article |
Language: | English |
Published: |
Nature Publishing Group
2018-09-01
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Series: | Nature Communications |
Online Access: | https://doi.org/10.1038/s41467-018-06324-9 |
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