Identifying the missing link in catalyst transfer polymerization

The mechanism for nickel-catalyzed catalyst transfer polycondensation of thiophenes to polythiophenes. Here the authors show experimental and computational evidence of structurally characterized square planar η 2-Ni(0)–thiophene species and their relevance to the mechanism of catalyst transfer polyc...

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Bibliographic Details
Main Authors: Weiying He, Brian O. Patrick, Pierre Kennepohl
Format: Article
Language:English
Published: Nature Publishing Group 2018-09-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-018-06324-9