UNDERSTANDING THE BEHAVIOUR OF SULPHUR-CENTRED RADICALS DURING POLYMER SELF-HEALING
High-level ab initio molecular orbital theory calculations have been used to study self-healing mechanism of materials based on thiuram disulfides and their derivatives (S=C(Z)S–SC(Z)=S, for Z = CH3, NEt2, N(Et)CH2CH2OH, Ph, Bz), and the effects of these Z-substituents on their efficacy. The relativ...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
Turkish Chemical Society
2016-11-01
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| Series: | Journal of the Turkish Chemical Society, Section A: Chemistry |
| Online Access: | http://dergipark.gov.tr/jotcsa/issue/27290/287305?publisher=turchemsoc |