Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis

Here, we report a simple synthetic strategy to the bridgehead vicinal diallylation of norbornene derivatives. These substrates are useful to generate propellanes via ring-closing metathesis. Single-crystal X-ray diffraction analysis of four compounds led to the realization of configurational correct...

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Main Authors:	Sambasivarao Kotha, Rama Gunta
Format:	Article
Language:	English
Published:	Beilstein-Institut 2016-08-01
Series:	Beilstein Journal of Organic Chemistry
Subjects:	norbornene propellane derivatives ring-closing metathesis single-crystal X-ray diffraction vicinal diallylation
Online Access:	https://doi.org/10.3762/bjoc.12.177

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record_format	Article
spelling	doaj-cad4db004b9b40aba91aec35e678af8d2021-03-02T10:05:25ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972016-08-011211877188310.3762/bjoc.12.1771860-5397-12-177Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesisSambasivarao Kotha0Rama Gunta1Department of Chemistry, Indian Institute of Technology-Bombay, Powai, Mumbai, IndiaDepartment of Chemistry, Indian Institute of Technology-Bombay, Powai, Mumbai, IndiaHere, we report a simple synthetic strategy to the bridgehead vicinal diallylation of norbornene derivatives. These substrates are useful to generate propellanes via ring-closing metathesis. Single-crystal X-ray diffraction analysis of four compounds led to the realization of configurational correction of earlier reported molecules.https://doi.org/10.3762/bjoc.12.177norbornenepropellane derivativesring-closing metathesissingle-crystal X-ray diffractionvicinal diallylation
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Sambasivarao Kotha Rama Gunta
spellingShingle	Sambasivarao Kotha Rama Gunta Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis Beilstein Journal of Organic Chemistry norbornene propellane derivatives ring-closing metathesis single-crystal X-ray diffraction vicinal diallylation
author_facet	Sambasivarao Kotha Rama Gunta
author_sort	Sambasivarao Kotha
title	Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis
title_short	Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis
title_full	Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis
title_fullStr	Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis
title_full_unstemmed	Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis
title_sort	bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis
publisher	Beilstein-Institut
series	Beilstein Journal of Organic Chemistry
issn	1860-5397
publishDate	2016-08-01
description	Here, we report a simple synthetic strategy to the bridgehead vicinal diallylation of norbornene derivatives. These substrates are useful to generate propellanes via ring-closing metathesis. Single-crystal X-ray diffraction analysis of four compounds led to the realization of configurational correction of earlier reported molecules.
topic	norbornene propellane derivatives ring-closing metathesis single-crystal X-ray diffraction vicinal diallylation
url	https://doi.org/10.3762/bjoc.12.177
work_keys_str_mv	AT sambasivaraokotha bridgeheadvicinaldiallylationofnorbornenederivativesandextensiontopropellanederivativesviaringclosingmetathesis AT ramagunta bridgeheadvicinaldiallylationofnorbornenederivativesandextensiontopropellanederivativesviaringclosingmetathesis
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Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis

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