Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis

Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis

Here, we report a simple synthetic strategy to the bridgehead vicinal diallylation of norbornene derivatives. These substrates are useful to generate propellanes via ring-closing metathesis. Single-crystal X-ray diffraction analysis of four compounds led to the realization of configurational correct...

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Bibliographic Details
Main Authors: Sambasivarao Kotha, Rama Gunta
Format: Article
Language:English
Published: Beilstein-Institut 2016-08-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
norbornene
propellane derivatives
ring-closing metathesis
single-crystal X-ray diffraction
vicinal diallylation
Online Access:https://doi.org/10.3762/bjoc.12.177

Internet

https://doi.org/10.3762/bjoc.12.177

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