Focus on Chemistry of the 10-Dioxane-<i>nido</i>-7,8-dicarba-undecahydrido Undecaborate Zwitterion; Exceptionally Easy Abstraction of Hydrogen Bridge and Double-Action Pathways Observed in Ring Cleavage Reactions with OH<sup>−</sup> as Nucleophile

Focus on Chemistry of the 10-Dioxane-<i>nido</i>-7,8-dicarba-undecahydrido Undecaborate Zwitterion; Exceptionally Easy Abstraction of Hydrogen Bridge and Double-Action Pathways Observed in Ring Cleavage Reactions with OH<sup>−</sup> as Nucleophile

Ring cleavage of cyclic ether substituents attached to a boron cage via an oxonium oxygen atom are amongst the most versatile methods for conjoining boron <i>closo</i>-cages with organic functional groups. Here we focus on much less tackled chemistry of the 11-vertex zwitterionic compoun...

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Bibliographic Details
Main Authors: Mário Bakardjiev, Suzan El Anwar, Dmytro Bavol, Zdeňka Růžičková, Bohumír Grűner
Format: Article
Language:English
Published: MDPI AG 2020-02-01
Series:Molecules
Subjects:
borane
carborane
dicarbollide ion
oxonium atom
nucleophilic substitution
Online Access:https://www.mdpi.com/1420-3049/25/4/814

Internet

https://www.mdpi.com/1420-3049/25/4/814

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