Crystal structure of {(R)-N2-[(benzo[h]quinolin-2-yl)methyl]-N2′-[(benzo[h]quinolin-2-yl)methylidene]-1,1′-binaphthyl-2,2′-diamine-κ4N,N′,N′′,N′′′}(trifluoromethanesulfonato-κO)zinc(II)} trifluoromethanesulfonate dichloromethane 1.5-solvate

Crystal structure of {(R)-N2-[(benzo[h]quinolin-2-yl)methyl]-N2′-[(benzo[h]quinolin-2-yl)methylidene]-1,1′-binaphthyl-2,2′-diamine-κ4N,N′,N′′,N′′′}(trifluoromethanesulfonato-κO)zinc(II)} trifluoromethanesulfonate dichloromethane 1.5-solvate

The zinc(II) atom in the title compound, [Zn(C48H31N4)(CF3SO3)](CF3SO3)·1.5CH2Cl2, adopts a distorted five-coordinate square-pyramidal geometry. It is coordinated by one trifluoromethanesulfonate ligand and four N atoms of the N2-[(benzo[h]quinolin-2-yl)methyl]-N2′-[(benzo[h]quinolin-2-yl)methyliden...

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Bibliographic Details
Main Authors: Shayna R. Skokan, Monica M. Reeson, Kayode D. Oshin, Anastasiya I. Vinokur, John A. Desper, Christopher J. Levy
Format: Article
Language:English
Published: International Union of Crystallography 2017-07-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
five-coordinate zinc(II) complex
chiral ligand
asymmetric catalysis
monohelical structure
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989017008027

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http://scripts.iucr.org/cgi-bin/paper?S2056989017008027

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