First Example of Direct Transformation of Alkylbenzenes to 1,3-Benzodioxoles by Oxidation with o-Chloranil

The reaction of alkyl-substituted benzenes with o-chloranil at an elevated temperature was found to give 4,5,6,7-tetrachloro-1,3-benzodioxoles via benzylic oxidation and subsequent acetal formation, albeit in poor yields.

Bibliographic Details
Main Authors: Tomoshige Kobayashi, Sheikh Maksudur Rahman
Format: Article
Language:English
Published: MDPI AG 2002-11-01
Series:Molecules
Subjects:
1
Online Access:http://www.mdpi.com/1420-3049/7/11/840/