Crystal structure of tetrakis(μ-n-butyrato-κ2O:O′)bis[chloridorhenium(III)](Re—Re)

Crystal structure of tetrakis(μ-n-butyrato-κ2O:O′)bis[chloridorhenium(III)](Re—Re)

With an inversion center at the mid-point of the two ReIII atoms, the title compound, [Re2Cl2{O2C(CH2)2CH3}4], exhibits a paddle-wheel or lantern-type structure with four n-butyrate groups bridging two ReIII atoms in a syn–syn fashion. The axial chloride ligands together with the Re—Re quadruple bon...

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Bibliographic Details
Main Authors: Michael P. Thomson, Natasha F. O'Rourke, Ruiyao Wang, Manuel A. S. Aquino
Format: Article
Language:English
Published: International Union of Crystallography 2014-10-01
Series:Acta Crystallographica Section E
Subjects:
crystal structure
dirhenium core
butyrate bridging ligand
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814020273

Internet

http://scripts.iucr.org/cgi-bin/paper?S1600536814020273

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