Living Radical Polymerization via Organic Superbase Catalysis

Living Radical Polymerization via Organic Superbase Catalysis

Organic superbases reacted with alkyl iodides (R–I) to reversibly generate the corresponding alkyl radicals (R•). Via this reaction, organic superbases were utilized as new and highly efficient organic catalysts in living radical polymerization. The superbase catalysts included guanidines, aminophos...

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Bibliographic Details
Main Authors: Lin Lei, Miho Tanishima, Atsushi Goto, Hironori Kaji
Format: Article
Language:English
Published: MDPI AG 2014-03-01
Series:Polymers
Subjects:
organic superbases
organic catalysts
living radical polymerization
reversible complexation mediated polymerization
radical chemistry
alkyl iodide
Online Access:http://www.mdpi.com/2073-4360/6/3/860

Internet

http://www.mdpi.com/2073-4360/6/3/860

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