Stabilisation of Exotic Tribromide (Br<sub>3</sub><sup>−</sup>) Anions via Supramolecular Interaction with A Tosylated Macrocyclic Pyridinophane. A Serendipitous Case.

Stabilisation of Exotic Tribromide (Br<sub>3</sub><sup>−</sup>) Anions via Supramolecular Interaction with A Tosylated Macrocyclic Pyridinophane. A Serendipitous Case.

<b> </b>Tetraaza-macrocyclic pyridinophane L-Ts, decorated with a <i>p</i>-toluenesulfonyl (tosyl; Ts) group, appear to be a useful tool to provide evidence on how the interplay of various supramolecular forces can help stabilise exotic anionic species such as tribromide (Br&...

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Bibliographic Details
Main Authors: Álvaro Martínez-Camarena, Matteo Savastano, Carla Bazzicalupi, Antonio Bianchi, Enrique García-España
Format: Article
Language:English
Published: MDPI AG 2020-07-01
Series:Molecules
Subjects:
N-heterocycles
anion complexes
anion- interactions
crystal structure
Hirshfeld surface analysis
Online Access:https://www.mdpi.com/1420-3049/25/14/3155

Internet

https://www.mdpi.com/1420-3049/25/14/3155

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