Syntheses and a Solid State Structure of a Dinuclear Molybdenum(V) Complex with Pyridine

A mononuclear complex [MoOCl4(H2O)]− readily forms a metal−metal bonded {Mo2O4}2+ core. A high content of pyridine in the reaction mixture prevents further aggregation of dinuclear cores into larger clusters and a neutral, dinuclear complex with the [Mo2O4Cl2(Py)4] composition is isolated as a produ...

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Bibliographic Details
Main Authors: Jon Zubieta, Barbara Modec
Format: Article
Language:English
Published: MDPI AG 2010-01-01
Series:Materials
Subjects:
Online Access:http://www.mdpi.com/1996-1944/3/1/150/