Syntheses and a Solid State Structure of a Dinuclear Molybdenum(V) Complex with Pyridine
A mononuclear complex [MoOCl4(H2O)]− readily forms a metal−metal bonded {Mo2O4}2+ core. A high content of pyridine in the reaction mixture prevents further aggregation of dinuclear cores into larger clusters and a neutral, dinuclear complex with the [Mo2O4Cl2(Py)4] composition is isolated as a produ...
Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
MDPI AG
2010-01-01
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Series: | Materials |
Subjects: | |
Online Access: | http://www.mdpi.com/1996-1944/3/1/150/ |