Hydrido(prolinato-κ2N,O)tris(trimethylphosphane-κP)iridium(III) hexafluoridophosphate

The title complex, [Ir(C5H8NO2)H(C3H9P)3]PF6, has two independent anion–cation pairs in the asymmetric unit. The geometry about each IrIII atom is pseudo-octahedral with a meridional arrangement of the P(CH3)3 ligands, N,O-bidentate coordination of prolinate and a hydride ligand trans to the prolina...

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Bibliographic Details
Main Authors: Joseph S. Merola, Christopher P. Roy
Format: Article
Language:English
Published: International Union of Crystallography 2014-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814001834