New Compounds with [As7]3– Clusters: Synthesis and Crystal Structures of the Zintl Phases Cs2NaAs7, Cs4ZnAs14 and Cs4CdAs14
Three new cluster compounds, Cs2NaAs7, Cs4ZnAs14, and Cs4CdAs14 were obtained from high temperature reactions. Their structures feature heptaarsenide [As7]3– anions, where the clusters in Cs4ZnAs14 and Cs4CdAs14 are dimerized by the linkers Zn and Cd, respectively. The bonding characteristics of the...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2011-06-01
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| Series: | Crystals |
| Subjects: | |
| Online Access: | http://www.mdpi.com/2073-4352/1/3/87 |